Research Guides

Department of Chemistry University of Oxford

Professor J.S. Foord

Chemistry of Nanomaterials and Surfaces

Nanomaterials are basically solids composed of (very small) particles of a size below 100 nm, and they are of interest in chemistry since they possess properties quite distinct from normal bulk materials.  A famous example of this phenomena is the behaviour of gold nanoparticles - whereas bulk gold is quite an inert substance , gold nanoparticles are much more reactive and indeed can be used as excellent catalysts for a range of reactions.  

Nanomaterials already have important uses, in our everyday lives and also as advanced functional materials.  Examples of the former include the use of titania nanopowders as pigments in paints and suntan creams ; examples of the latter include the uses of platinum nanoparticles as advanced (electro-) catalysts, and the addition of nanoparticles to polymers  to induce specific functionality such as biocidal properties. 

The group is  concerned with the chemical synthesis of new solid-state nanomaterials, to enable novel applications, along with closely related studies on the surface chemistry of materials.  Apart from the fabrication of the materials, we also carry out detailed  physical characterisation using a comprehensive range of physical methods such as electron microscopy, atomic force microscopy, XRD, scanning electrochemical microscopy, dynamic electrochemistry, Raman, Ir and nmr spectroscopies and XPS, and measure functional performance for particular applications. The investigations raise intriguing academic challenges since achieving an understanding of the factors controlling chemical structure, stability, and kinetics of nanomaterials and interfaces often requires very new concepts and methodologies. 

Projects of current interest include: 

1. Nanomaterials for sustainable ("green") energy applications

A future energy vision to reduce the emission of greenhouse gases is based on the use of hydrogen as a fuel source, which can be “burnt” to form water either in a conventional combustion process, or more likely via its use in  fuel cells to produce electricity. For most of these latter types of application (eg. electric cars, laptops), a portable form of hydrogen is needed, for which 

possibilities such as cryogenic or high-pressure storage of hydrogen are unattractive. We are studying chemical routes for the generation of “hydrogen on demand” which involve heterogeneous reactions at the interface between liquids and nanodisperse solids.  

A related project is the development of improved catalysts for use in fuel cells.  At present these devices contain Pt nanoparticles which catalyse the fuel cell chemistry, and the cost of the Pt can be prohibitive. We are therefore engaged in the search for better catalysts, either by combining Pt with other elements, or using improved Pt nanoparticle synthesis methods.

We have a particular interest in nanocarbons. These encompass a range of carbon forms, such as nanodiamonds, graphene platelets, carbon onions and carbon nanotubes.  They are in part of interest since it is possible to assemble them into thin films with high porosity and incredible surface areas. We are exploring their use as battery electrodes and in supercapacitors.

 
2.  Fabrication and applications of diamond films for chemical sensors

Chemical sensors are devices which measure the composition of some gas or liquid phase medium , normally producing an electrical signal. An important area is biosensing – the measurement of biochemicals in living tissue – and we are currently engaged developing a range of biosensors, for chemicals such as neurotransmitters and glucose.

The sensor design is of an electrochemical nature, and normally involves the modification of electrode surfaces with enzymes and catalytic particles to produce a selective chemical reaction with the target analyte. This produces a chemical which can be oxidised by the electrode to produce an electrical signal current. 
 
We are particularly interested in the use of synthetic diamond coatings in this area. These polycrystalline diamond coatings can be made electrically conducting and have many  advantages for this type of application.

 

3. Self-assembly of nanomaterials

Nanostructured materials are often assembled into larger structures by a process known as self-assembly, whereby chemical forces drive the arrangement of the nanoparticles of interest into larger structures, a process also widely used in nature (e.g. opalescence materials in butterfly wings!)   

We are particularly interested in the use of self-assembly for the fabrication of nanostructured coatings based on novel forms of carbon and in so-called polymer nanocomposites.  As the name suggests, these are polymers with embedded nanoparticles which can control polmer properties such as related to wear and friction, superhydrophobicity, antibacteriocidal activity, dielectric behaviour, flammability etc.

 

1.            Lawrence, K., G.W. Nelson, J.S. Foord, M. Felipe-Sotelo, N.D.M. Evans, J.M. Mitchels, T.D. James, F. Xia, and F. Marken, "Hydrothermal wrapping" with poly(4-vinylpyridine) introduces functionality: pH-sensitive core-shell carbon nanomaterials. J. Mater. Chem. A. 1(14): p. 4559-4564, 2013.

2.            Liu, B., J. Hu, and J.S. Foord, Electrochemical detection of DNA hybridization by a zirconia modified diamond electrode. Electrochem. Commun. 19: p. 46-49, 2012.

3.            Lu, X., J.-P. Hu, J.S. Foord, and Q. Wang, Electrochemical deposition of Pt-Ru on diamond electrodes for the electrooxidation of methanol. J. Electroanal. Chem. 654(1-2): p. 38-43, 2011.

4.            Subramanian, P., Y. Coffinier, D. Steinmuller-Nethl, J. Foord, R. Boukherroub, and S. Szunerits, Diamond nanowires decorated with metallic nanoparticles: A novel electrical interface for the immobilization of histidinylated biomolecuels. Electrochim. Acta, 2013 Ahead of Print.

5.            Zhou, X., J. Qu, F. Xu, J. Hu, J.S. Foord, Z. Zeng, X. Hong, and S.C.E. Tsang, Shape selective plate-form Ga2O3 with strong metal-support interaction to overlying Pd for hydrogenation of CO2 to CH3OH. Chem. Commun. (Cambridge, U. K.). 49(17): p. 1747-1749, 2013.