Research Guides

Department of Chemistry University of Oxford

Dr Zoe Turner

SCG Research Fellow

Inorganic Chemistry

Chemistry Research Laboratory
12 Mansfield Road
Oxford
OX1 3TA.

T +44 (0)1865 285157 (office)
T +44 (0)1865 285135 (lab)
E zoe.turner@chem.ox.ac.uk


Working with Dermot O'Hare

 

 

Main group and organometallic chemistry

Our key research interest is the study of reactive, low-valent main group and organometallic complexes; these complexes are targetted with careful ligand design which often utilises metal-ligand co-operativity. By understanding the fundamental structure and bonding of these complexes, we aim to uncover new stoichiometric and catalytic reactivity with small molecules.


Selected publications

i) Main group and organometallic complexes: synthesis, characterisation and small molecule activation.

Carbon oxygenate transformations by actinide compounds and catalysts. Arnold, P. L.; Turner, Z. R. Nat. Rev. Chem. 2017, 1, 0002. [link]

Ammonia activation, H2 evolution and nitride formation from a molybdenum complex with a chemically and redox non-innocent ligand. Margulieux, G. W.; Bezdek, M. J.; Turner, Z. R.; Chirik, P. J. J. Am. Chem. Soc. 2017, 139, 6110-6113. [link]

Chemically non-innocent cyclic (alkyl)(amino)carbenes: ligand rearrangement, C−H and C−F bond activation. Turner, Z. R. Chem. Eur. J. 2016, 22, 11461-11468. [link]

Group 1 and 2 cyclic (alkyl)(amino)carbene complexes. Turner, Z. R.; Buffet, J.-C. Dalton Trans. 2015, 44, 12985-12989. [link]

  

Molecular pnictogen activation by rare earth and actinide complexes. Turner, Z. R. Inorganics 2015, 3, 597-635. [link]

Synthesis and ligand modification chemistry of a molybdenum dinitrogen complex: redox and chemical activity of a bis(imino)pyridine ligand. Margulieux, G. W.; Turner, Z. R.; Chirik, P. J. Angew. Chem. Int. Ed. 2014, 53, 14211-14215. [link]

Carbon monoxide coupling and functionalisation at a simple uranium coordination complex. Arnold, P. L.; Turner, Z. R.; Bellabarba, R. M.; Tooze, R. P. Chem. Sci. 2011, 2, 77-79. [link]

Addition-elimination reactions across the M−C bond of metal N-heterocyclic carbenes. Turner, Z. R.; Bellabarba, R.; Tooze, R. P.; Arnold, P. L. J. Am. Chem. Soc. 2010, 132, 4050-4051. [link]

ii) Catalysis.

Tungsten imido catalysts for selective ethylene dimerisation. Wright, C. M. R.; Turner, Z. R.; Buffet, J.-C.; O'Hare, D. Chem. Commun. 2016, 52, 2850-2853. [link]

Titanium and zirconium permethylpentalene complexes, Pn*MCpRX, as ethylene polymerization catalysts.  Fraser, D. A. X.; Turner, Z. R.; Buffet, J.-C.; O’Hare, D. Organometallics 2016, 35, 2664-2674. [link]

Chiral group 4 cyclopentadienyl complexes and their use in polymerization of lactide monomers. Turner, Z. R.; Buffet,  J.-C.; O'Hare, D. Organometallics 2014, 33, 3891-3903. [link]